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2020/6/24 -Before the past decade, all examples of Ni-catalyzed asymmetric cross-couplings fell into the category of redox-neutral transformations.
2023/5/23 -This study presents a novel nickel-catalyzed electrochemical methodology for reductive cross-electrophile coupling. The method enables C(sp2)–C( ...
2020/4/2 -Ni(I)–C sp3 complexes could undergo insertion via nucleophilic attack of the alkyl groups to CO2 (intermediate 14), where sp and sp2 ...
2023/11/1 -A general method for the Ni-catalyzed Buchwald–Hartwig amination of (hetero)aryl chlorides using both anilines and aliphatic amines under ...
2021/11/5 -Direct coupling of unactivated alcohols remains a challenge in current synthetic chemistry. We herein demonstrate a strategy building upon ...
2023/11/16 -The key reactive Ni(II)H species for chain-walking could be generated in situ either in a polarity-reversed fashion relying on stoichiometric ...
2022/11/9 -A nickel-catalyzed reductive cross-coupling of cyclopropylamine NHP esters with (hetero)aryl halides is reported.
2023/9/1 -Due to the unique properties of nickel, Ni-catalyzed defluorinative cross-couplings have been greatly developed in the past few decades as ...
2021/11/5 -Direct coupling of unactivated alcohols remains a challenge in current synthetic chemistry. We herein demonstrate a strategy building upon ...
This Account presents the development of a suite of stereospecific alkyl-alkyl cross-coupling reactions employing nickel catalysts.